When you search for a food such as avocados, you might look at the nutrition information and see the total fat grams is more than the sum of the three individual fatty acids (saturated fats, polyunsaturated fats and monounsaturated fats). Don't worry, while the total fats section of the nutrition charts may appear to be off, they're correct. The disparity isn't due to math errors (although rounding up or down may cause slight differences); the major reason is because there are other types of fatty substances present. These substances (phospholipids, glycerol and sterols) are included in the total fat, but they're not considered to be part any of the three fatty acid groups.
You won't find the phospholipids or glycerols listed in the nutrition information charts, however you will find the sterols. The best-known sterol is cholesterol, which is found in animals as well as the phytosterols (beta-sitosterol, stigmasterol and campesterol), which are found in plants.
Source:
United States Department of Agriculture. "USDA Nutrient Database: Frequently Asked Questions." Accessed July 13, 2010. .

